Open Access Peer-reviewed Research Article

Extraction and analysis of back-sheet layer from waste silicon solar modules

Main Article Content

Chitra Chitra
Dheeraj Sah
Parveen Saini
Sushil kumar corresponding author

Abstract

The back-sheet shields the solar panel from UV rays, moisture, dust, and other environmental factors. With the enormous growth of the solar industry year after year, the demand for recycling is also increasing rapidly. In the present study, the back-sheet layer was extracted from a waste crystalline silicon PV module by thermally heating the module at 130˚C temperature. Various characterization techniques, including Raman, FTIR, SEM-EDAX, XRD, and TGA, were used to examine extracted back-sheet layer properties for its reuse. The Raman and FTIR spectra of extracted back-sheet are quite similar to those of reference PET back-sheet, indicating that no significant changes in composition occurred during the extraction process. The extracted back-sheet has a composition of carbon and oxygen as witnessed from EDAX spectroscopy. The extracted back sheet maintained its semicrystalline behavior as that of the reference back sheet, observed by XRD spectroscopy. Thermogravimetric analysis revealed that the thermal stability of extracted back-sheet is up to 252˚C in the air environment and up to 315˚C in the inert environment. Thermal degradation of extracted back-sheet is a two-step process in an air environment observed by differential thermogravimetry. The observed properties of extracted back-sheet are comparable to those of commercially available back-sheet, and the same may be reused in solar and polymer industries after appropriate processing.

Keywords
solar waste, polymers, back sheet, recycling

Article Details

How to Cite
Chitra, C., Sah, D., Saini, P., & kumar, S. (2022). Extraction and analysis of back-sheet layer from waste silicon solar modules. Chemical Reports, 4(1), 256-263. https://doi.org/10.25082/CR.2022.01.004

References

  1. Irena I. End-of-Life Management: Solar Photovoltaic Panels, 2016. https://www.irena.org
  2. Zhang L and Ciftja A. Recycling of solar cell silicon scraps through filtration, Part I: Experimental investigation. Solar Energy Materials and Solar Cells, 2008, 92(11): 1450-1461. https://doi.org/10.1016/j.solmat.2008.06.006
  3. Doi T, Tsuda I, Unagida H, et al. Experimental study on PV module recycling with organic solvent method. Solar Energy Materials and Solar Cells, 2001, 67(1-4): 397-403. https://doi.org/10.1016/S0927-0248(00)00308-1
  4. Chitra D, Sah K, Lodhi C, et al. Structural composition and thermal stability of extracted EVA from silicon solar modules waste. Solar Energy, 2020, 211: 74-81. https://doi.org/10.1016/j.solener.2020.09.039
  5. Paiano A. Photovoltaic waste assessment in Italy. Renewable and Sustainable Energy Reviews, 2015, 41: 99-112. https://doi.org/10.1016/J.RSER.2014.07.208
  6. Tammaro M, Salluzzo A, Rimauro J, et al. Experimental investigation to evaluate the potential environmental hazards of photovoltaic panels. Journal of Hazardous Materials, 2016, 306(5): 395-405. https://doi.org/10.1016/J.JHAZMAT.2015.12.018
  7. Harnisch J. Study on photovoltaic panels supplementing the assessment impact in the recast of WEEE directive, Bio-Intelligence Service. European Commission (DG ENV), 2011.
  8. Freiburg. Photovoltaics Report, 2021. https://www.ise.fraunhofer.de
  9. Jing T and Yu S. Review on feasible recycling pathways and technologies of solar photovoltaic modules. Solar Energy Materials and Solar Cells, 2015, 141: 108-124. https://doi.org/10.1016/J.SOLMAT.2015.05.005
  10. Bruton TM. General trends about photovoltaics based on crystalline silicon. Solar Energy Materials and Solar Cells, 2002, 72: 3-10. https://doi.org/10.1016/S0927-0248(01)00145-3
  11. Fernández LJ, Ferrer R, Aponte DF, et al. Recycling silicon solar cell waste in cement-based systems. Solar Energy Materials & Solar Cells, 2011, 95(7): 1701-1706. https://doi.org/10.1016/J.SOLMAT.2011.01.033
  12. Latunussa CEL, Ardente F, Blengini GA, et al. Life Cycle Assessment of an innovative recycling process for crystalline silicon photovoltaic panels. Solar Energy Materials and Solar Cells, 2016, 156: 101-111. https://doi.org/10.1016/j.solmat.2016.03.020
  13. Polanský P, Pinkerová M, Bartůňková M, et al. Mechanical behavior and thermal stability of eva encapsulant material used in photovoltaic modules. Journal of Electrical Engineering, 2013, 64: 361-365. https://doi.org/10.2478/jee-2013-0054
  14. Park J, Kim AW, Cho BN, et al. An eco-friendly method for reclaimed silicon wafers from a photovoltaic module: From separation to cell fabrication. Green Chemistry, 2016, 18(6): 1706-1714. https://doi.org/10.1039/c5gc01819f
  15. Padoan FCSM, Altimari P and Pagnanelli F. Recycling of end of life photovoltaic panels: A chemical prospective on process development. Solar Energy, 2019, 177: 746-761. https://doi.org/10.1016/j.solener.2018.12.003
  16. Shin J, Park J and Park N. A method to recycle silicon wafer from end-of-life photovoltaic module and solar panels by using recycled silicon wafers. Solar Energy Materials and Solar Cells, 2017, 162: 1-6. https://doi.org/10.1016/J.SOLMAT.2016.12.038
  17. Strachala D, Hylsk J, Vank J, et al. Methods for recycling photovoltaic modules and their impact on environment and raw material extraction. Acta Montanistica Slovaca, 2017, 22(3): 257-269.
  18. Larsen K. End-of-life PV: then what? Renewable Energy Focus, 2009, 10: 48-53. https://doi.org/10.1016/S1755-0084(09)70154-1
  19. Tammaro M, Rimauro J, Fiandra V, et al. Thermal treatment of waste photovoltaic module for recovery and recycling: Experimental assessment of the presence of metals in the gas emissions and in the ashes. Renewable Energy, 2015, 81: 103-112. https://doi.org/10.1016/J.RENENE.2015.03.014
  20. Zhang J, Lv F, Ma LY, et al. The status and trends of crystalline silicon PV module recycling treatment methods in Europe and China. Advanced Materials Research, 2013, 724: 200-204. https://www.scientific.net/AMR.724-725.200
  21. Berger W, Simon FG, Weimann K, et al. A novel approach for the recycling of thin film photovoltaic modules, Resources. Conservation and Recycling, 2010, 54: 711-718. https://doi.org/10.1016/J.RESCONREC.2009.12.001
  22. Granata G, Pagnanelli F, Moscardini E, et al. Recycling of photovoltaic panels by physical operations. Solar Energy Materials and Solar Cells, 2014, 123: 239-248. https://doi.org/10.1016/J.SOLMAT.2014.01.012
  23. Marwede M, Berger W, Schlummer M, et al. Recycling paths for thin-film chalcogenide photovoltaic waste – Current feasible processes. Renewable Energy, 2013, 55: 220-229. https://doi.org/10.1016/J.RENENE.2012.12.038
  24. Pagnanelli F, Moscardini E, Granata G, et al. Physical and chemical treatment of end of life panels: An integrated automatic approach viable for different photovoltaic technologies. Waste Management, 2017, 59: 422-431. https://doi.org/10.1016/j.wasman.2016.11.011
  25. Huang WH, Shin WJ, Wang L, et al. Strategy and technology to recycle wafer-silicon solar modules. Solar Energy, 2017, 144: 22-31. https://doi.org/10.1016/j.solener.2017.01.001
  26. Mahmoudi S, Huda N, Alavi Z, et al. End-of-life photovoltaic modules: A systematic quantitative literature review, Resources. Conservation and Recycling, 2019, 146: 1-16. https://doi.org/10.1016/j.resconrec.2019.03.018
  27. Xu Y, Li J, Tan Q, et al. Global status of recycling waste solar panels: A review. Waste Management, 2018, 75: 450-458. https://doi.org/10.1016/J.WASMAN.2018.01.036
  28. Lin CC, Krommenhoek PJ, Watson SS, et al. Chemical depth profiling of photovoltaic backsheets after accelerated laboratory weathering. Proceedings of SPIE - The International Society for Optical Engineering, 2014, 9179: 289-299. https://doi.org/10.1117/12.2066400
  29. Donelli I, Taddei P, Smet PF, et al. Enzymatic surface modification and functionalization of PET: A water contact angle, FTIR, and fluorescence spectroscopy study. Biotechnology and Bioengineering, 2009, 103: 845-856. https://doi.org/10.1002/bit.22316
  30. Samsaray T and Potiyaraj P. Preparation and properties of graphene / poly (Ethylene terephthalate) composite fibers. Solid State Phenomena, 2020, 304: 9-14. https://doi.org/10.4028/www.scientific.net/ssp.304.9
  31. Japu C, Antxon M, Alla A, et al. Bio-based poly(ethylene terephthalate) copolyesters made from cyclic monomers derived from tartaric acid. Polymer, 2014, 55(10): 2294-2304. https://doi.org/10.1016/j.polymer.2014.03.018